![]() ![]() “They’re not disgusting!” Nathan Lane explains to his sons. So get ready, because this Halloween, “sewer boys” is gonna be the hottest couples costume for boyfriend twins. The film will open TIFF’s Midnight Madness and be released into the world on September 29. Directed by Larry Charles ( Borat) and co-starring Bowen Yang (as God), the film’s first trailer has a cavalcade of dick jokes, vocal inflections, and beautiful melodies. If that sounds similar to something you’ve seen before, ask yourself, “Did Lindsay Lohan have sewer boys and Megan Thee Stallion?” No! That redhead just had fencing. The two decide to trick their parents into getting back together. ![]() A24’s first movie musical is not so much Sound of Music as it is “queer entropy, with music.” Written by and starring Josh Sharp and Aaron Jackson, and based on their stage show F*cking Identical Twins, the movie follows two businessmen who discover they are identical twins, separated at birth, with one living with his mother played by Megan Mullally and one with his father, Nathan Lane. ![]() S m i x r is expected to be vibrational to a large extent, but not entirely so. The former is the entropy of mixing accessible to the liquid, the latter is the mixing entropy in the vitrified mixture. Thus, as solubility increases, entropy associated with mixing increases.Dicks: The Musical is ready to bring chaos to your local multiplex. The entropy of mixing consists of two parts, a configurational portion ( S m i x c), and a residual part ( S m i x r). When you do the same calculation for #"1 g RbCl"#, which is less soluble, you should get #color(blue)"0.4686 J/K"#. Now that we have everything, we can determine #DeltaS_"mix"# for mixing #"1 g NaCl"# into water: Lastly, we should know that since entropy has units of #"J/K"#, we are using #R = "8.314472 J/mol"cdot"K"#. Strecker Synthesis: synthesis of a racemic mixture of L and D amino acids from. #=#"2.7673 mol" + "0.017112 mol" = color(green)("2.7845 mol")# Proteins fold into a state that maximizes the entropy of the system and. The last variable we don't know is the total number of #"mol"#s: Where #i ne j# because #"NaCl" ne "H"_2"O"#. Now, we can determine the mole fraction of each. We are only looking at entropy of mixing. Again, ignore Debye-Huckel theory for simplicity. You can do a similar calculation using #"RbCl"# on your own. With this, we know that entropy increases as more solute is dissolved.Īs a specific calculation example, let's see what the entropy is for dissolving each #"1 g"# of each salt in water.įor #"1 g NaCl"#, let's determine the moles of each component at #25^o"C"#. mole fraction #chi# of the ideal solute, following the experiment above, looks like this: The graph for entropy of mixing #DeltaS_"mix"# vs. You can also do this in Excel if you want to.įor each one, because we have normalized this to a fraction or percentage, the graph's curvature looks the same for each solute when assuming that both are ideal. Let's say we have #"50 mL"# of water and we add a mass of the salt from #0.01# up until and including #"1 g"# in #"0.01 g"#-increments ( #100# separate solvation trials). Now, let us consider mixing each salt into water, where water is component #1# and the salt is component #2#. Where #R# is the universal gas constant, #n# is the total number of #"mol"#s of both the solute and solvent combined, and #chi_i# is the mole fraction of component #i#.ĮNTROPY OF MIXING VS MOLE FRACTION OF DISSOLVED SOLUTE ![]() When assuming a simple ideal binary mixture, we have the following equation: There is an entropy associated with mixing two compounds together, called #DeltaS_"mix"#. Let's compare #"NaCl"# with #"RbCl"# (solubilities are #359# and #91 "g/L"#, respectively), but ignore Debye-Huckel theory on this for simplicity. As solubility increases, entropy associated with mixing a solute into a solvent increases. ![]()
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